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As molten iron cools past its freezing point of 1538 °C, it crystallizes into its δ allotrope, which has a body-centered cubic (bcc) crystal structure.As it cools further to 1394 °C, it changes to its γ-iron allotrope, a face-centered cubic (fcc) crystal structure, or austenite.As the iron passes through the Curie temperature there is no change in crystalline structure, but there is a change in "domain structure", where each domain contains iron atoms with a particular electronic spin.In unmagnetized iron, all the electronic spins of the atoms within one domain have the same axis orientation; however, the electrons of neighboring domains have other orientations with the result of mutual cancellation and no magnetic field.

Because of its significance for planetary cores, the physical properties of iron at high pressures and temperatures have also been studied extensively.

Iron is also the metal at the active site of many important redox enzymes dealing with cellular respiration and oxidation and reduction in plants and animals.

A human male of average height has about 4 grams of iron in his body, a female about 3.5 grams.

Unlike the metals that form passivating oxide layers, iron oxides occupy more volume than the metal and thus flake off, exposing fresh surfaces for corrosion.

Iron metal has been used since ancient times, although copper alloys, which have lower melting temperatures, were used even earlier in human history.

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